Which of the following is correctly matched?

For any integer $n \geq 2$,let $I_n = \int \tan^n x \, dx$. If $I_n = \frac{1}{a} \tan^{n-1} x - b I_{n-2}$ for $n \geq 2$,then the ordered pair $(a, b)$ equals to

Vapour pressure in $mm \ Hg$ of $0.1 \ mole$ of urea in $180 \ g$ of water at $25^{\circ} C$ is (The vapour pressure of water at $25^{\circ} C$ is $24 \ mm \ Hg$)

$A$ radioactive material decays by simultaneous emission of two particles with respective half-lives $1620 \, years$ and $810 \, years$. The time, in years, after which one-fourth of the material remains is

Sulphuric acid reacts with $PCl_5$ to give

Let $\overrightarrow{a}=a_1 \hat{i}+a_2 \hat{j}+a_3 \hat{k}$.
Assertion $(A)$: The identity $|\overrightarrow{a} \times \hat{i}|^2+|\overrightarrow{a} \times \hat{j}|^2+|\overrightarrow{a} \times \hat{k}|^2=2|\overrightarrow{a}|^2$ holds for $\overrightarrow{a}$.
Reason $(R)$: $\overrightarrow{a} \times \hat{i}=a_3 \hat{j}-a_2 \hat{k}$, $\overrightarrow{a} \times \hat{j}=a_1 \hat{k}-a_3 \hat{i}$, and $\overrightarrow{a} \times \hat{k}=a_2 \hat{i}-a_1 \hat{j}$.
Which of the following is correct?