$t_{1/2} =$ constant confirms the first order reaction. If $a^2 t_{1/2} =$ constant,it confirms that the order of reaction is ($a =$ initial concentration of reactant).

  • A
    $0$
  • B
    $1$
  • C
    $2$
  • D
    $3$

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The rate constant for the reaction,$2N_2O_5 \to 4NO_2 + O_2$ is $3.0 \times 10^{-4} \ s^{-1}$. If the reaction starts with $1.0 \ mol \ L^{-1}$ of $N_2O_5$,calculate the rate of formation of $NO_2$ at the moment when the concentration of $O_2$ is $0.1 \ mol \ L^{-1}$.

$[A]_0 / \text{mol } L^{-1}$ $t_{1/2} / \text{min}$
$0.100$ $200$
$0.025$ $100$

For a given reaction $R \rightarrow P$,$t_{1/2}$ is related to $[A]_0$ as given in the table:
Given: $\log 2 = 0.30$
Which of the following is true?
$A.$ The order of the reaction is $1/2$.
$B.$ If $[A]_0$ is $1 \text{ M}$,then $t_{1/2}$ is $200 \sqrt{10} \text{ min}$.
$C.$ The order of the reaction changes to $1$ if the concentration of reactant changes from $0.100 \text{ M}$ to $0.500 \text{ M}$.
$D.$ $t_{1/2}$ is $800 \text{ min}$ for $[A]_0 = 1.6 \text{ M}$.
Choose the correct answer from the options given below:

Rate of reaction is given by the following rate law $-\frac{d[C]}{dt} = \frac{k_1 [C]}{1 + k_2 [C]}$. Determine the order of reaction when the concentration $[C]$ is very high.

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