CCl_3CHO xrightarrow[KOH]{Conc.} Main product | vedclass

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(D) The reaction of $CCl_3CHO$ (chloral) with concentrated $KOH$ is an example of the Cannizzaro reaction. Since $CCl_3CHO$ does not have any $\alpha$

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$(A)$ and $(B)$ both

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(D) The reaction of $CCl_3CHO$ (chloral) with concentrated $KOH$ is an example of the Cannizzaro reaction. Since $CCl_3CHO$ does not have any $\alpha$-hydrogen,it undergoes self-oxidation and reduction (disproportionation). The aldehyde group is oxidized to a carboxylate salt $(CCl_3COOK)$ and reduced to an alcohol $(CCl_3CH_2OH)$. Therefore,both $CCl_3CH_2OH$ and $CCl_3COOK$ are formed as products.

$CCl_3CHO \xrightarrow[KOH]{Conc.}$ Main product is

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