Under identical reaction conditions,for a reactant with an initial concentration of $1.386 \, M$,the time taken for the concentration to become half is $40 \, s$ for a first-order reaction and $20 \, s$ for a zero-order reaction. The ratio of the rate constant of the first-order reaction $(K_1)$ to the rate constant of the zero-order reaction $(K_0)$ is ......... $mol \, L^{-1}$.

Under the same reaction conditions, initial concentration of $1.386 \ mol \ dm^{-3}$ of a substance becomes half in $40 \ s$ and $20 \ s$ through first-order and zero-order kinetics respectively. Ratio $\left(\frac{k_{1}}{k_{0}}\right)$ of the rate constants for first-order $\left(k_{1}\right)$ and zero-order $\left(k_{0}\right)$ of the reactions is

Given below are two statements: $R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}$ and $1 \text{ cal} = 4.2 \text{ J}$.
Statement $I$: When $E_a = 12.6 \text{ kcal/mol}$, the room temperature rate constant is doubled by a $10 \text{ }^\circ\text{C}$ increase in temperature ($298 \text{ K}$ to $308 \text{ K}$).
Statement $II$: For a first-order reaction $A \to B$, the graph of half-life $(t_{1/2})$ versus initial concentration $[A]_o$ is a straight line passing through the origin.
In the light of the above statements, choose the correct answer from the options given below:

Match the rate expressions in List-$I$ for the decomposition of $X$ with the corresponding profiles provided in List-$II$. $X_s$ and $k$ are constants having appropriate units.

The rate of a chemical reaction depends upon

Which one of the following represents a complex reaction?