The IUPAC name of (CO)_3Fe(mu-CO)_3Fe(CO)_3 i | vedclass

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Question

(A) The given complex is $Fe_2(CO)_9$,which can be represented as $(CO)_3Fe(\mu-CO)_3Fe(CO)_3$. In this structure,there are $3$ bridging carbonyl grou

Vedclass · Accepted Answer

Tri-$\mu$-carbonyl bis(tricarbonyliron$(0)$)

Vedclass · Answer

(A) The given complex is $Fe_2(CO)_9$,which can be represented as $(CO)_3Fe(\mu-CO)_3Fe(CO)_3$. In this structure,there are $3$ bridging carbonyl groups $(\mu-CO)$ and $6$ terminal carbonyl groups $(CO)$. Each iron atom is bonded to $3$ terminal carbonyls and $3$ bridging carbonyls. The $IUPAC$ name is constructed by identifying the bridging ligands first,followed by the metal centers. The correct name is $Tri-\mu-carbonyl-bis(tricarbonyliron(0))$. Thus,the correct option is $A$.

The $IUPAC$ name of $(CO)_3Fe(\mu-CO)_3Fe(CO)_3$ is ........

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