Based on the given stability constants (hypothetical values),predict which is the strongest ligand?

  • A
    $Cu^{2+} + 4NH_3 \rightleftharpoons [Cu(NH_3)_4]^{2+} \quad (K = 4.5 \times 10^{11})$
  • B
    $Cu^{2+} + 4CN^- \rightleftharpoons [Cu(CN)_4]^{2-} \quad (K = 2.0 \times 10^{27})$
  • C
    $Cu^{2+} + 2en \rightleftharpoons [Cu(en)_2]^{2+} \quad (K = 3.0 \times 10^{15})$
  • D
    $Cu^{2+} + 4H_2O \rightleftharpoons [Cu(H_2O)_4]^{2+} \quad (K = 9.5 \times 10^8)$

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Compound $PdCl_4 \cdot 6H_2O$ is a hydrated complex; $1 \ m$ aqueous solution of it has a freezing point of $269.28 \ K$. Assuming $100\%$ ionization of the complex,calculate the molecular formula of the complex ($K_f$ for water $= 1.86 \ K \ kg \ mol^{-1}$,freezing point of pure water $= 273 \ K$).

How does ammonia react with a solution of $Cu^{2+}$?

$CuSO_4$ solution reacts with excess of $KCN$ solution to form:

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The correct increasing order of stability of the complexes based on $\Delta_o$ value is $:$
$I. \ [Mn(CN)_6]^{3-}$
$II. \ [Co(CN)_6]^{4-}$
$III. \ [Fe(CN)_6]^{4-}$
$IV. \ [Fe(CN)_6]^{3-}$

Which complex cannot ionise in solution?

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