Iodoform gives a precipitate with AgNO_3 on h | vedclass

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(C) The reaction of haloalkanes with $AgNO_3$ depends on the ease of formation of carbocations or the ease of breaking the $C-X$ bond. In iodoform $(C

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The $C-I$ bond in iodoform is weak,whereas the $C-Cl$ bond in chloroform is strong

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(C) The reaction of haloalkanes with $AgNO_3$ depends on the ease of formation of carbocations or the ease of breaking the $C-X$ bond. In iodoform $(CHI_3)$,the $C-I$ bond is much weaker than the $C-Cl$ bond in chloroform $(CHCl_3)$ due to the larger size of the iodine atom and lower bond dissociation energy. Therefore,$CHI_3$ easily releases $I^-$ ions which react with $Ag^+$ to form a yellow precipitate of $AgI$,whereas $CHCl_3$ does not readily release $Cl^-$ ions under these conditions.

Iodoform gives a precipitate with $AgNO_3$ on heating,but chloroform does not because ..........

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