Which of the following pairs of liquids shows a positive deviation from Raoult's law?

$A$ mixture of toluene and benzene forms a nearly ideal solution. Assume $p_{B}^{\circ}$ and $p_{T}^{\circ}$ to be the vapour pressures of pure benzene and toluene,respectively. The slope of the line obtained by plotting the total vapour pressure versus the mole fraction of benzene is $....$

Which of the following statements is correct regarding a solution of two compounds $A$ and $B$ exhibiting positive deviation from ideal behaviour?

Liquids $A$ and $B$ form an ideal solution in the entire composition range. At $350 \ K$,the vapour pressures of pure $A$ and pure $B$ are $7 \times 10^3 \ Pa$ and $12 \times 10^3 \ Pa$,respectively. The composition of the vapour in equilibrium with a solution containing $40 \ \text{mole percent}$ of $A$ at this temperature is

$A$ mixture of toluene and benzene boils at $100^{\circ} C$. Assuming ideal behaviour,the mole fraction of toluene in the mixture is closest to (Vapour pressures of pure toluene and pure benzene at $100^{\circ} C$ are $0.742 \ bar$ and $1.800 \ bar$,respectively. $1 \ atm = 1.013 \ bar$)

At $88\,^oC$,the vapor pressure of benzene is $900 \, \text{torr}$ and that of toluene is $360 \, \text{torr}$. What is the mole fraction of benzene in the mixture with toluene that will boil at $88\,^oC$ and $1 \, \text{atm}$ pressure,assuming it forms an ideal solution?