Which of the following cannot act as a buffer solution?

Which of the following does not form a buffer solution?

$A$ sample of $100 \ mL$ of $0.10 \ M$ acid $HA$ $(K_a = 1 \times 10^{-5})$ is titrated with standard $0.2 \ M \ KOH$. How many $mL$ of $KOH$ will have to be added when the $pH$ in the titration flask will be $5.00$?

Which of the following buffer solutions will have the highest acidic character?

The $pH$ of an acidic buffer mixture is

One litre buffer solution was prepared by adding $0.10 \ mol$ each of $NH_3$ and $NH_4Cl$ in deionised water. The change in $pH$ on addition of $0.05 \ mol$ of $HCl$ to the above solution is $............ \times 10^{-2}$ ($Nearest$ $integer$) ($Given$: $pK_b$ of $NH_3 = 4.745$ and $\log_{10} 3 = 0.477$)