The enthalpy of solution of $NaOH_{(s)}$ in water is $-41.6 \ kJ \ mol^{-1}$. When $NaOH_{(s)}$ is dissolved in water,the temperature of the water will ..........

  • A
    increase
  • B
    decrease
  • C
    remain unchanged
  • D
    change unpredictably

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The atomisation enthalpy of $CH_4$ is $1660 \ kJ \ mol^{-1}$. The $C-H$ bond enthalpy of each successive step in $CH_4$ $\rightarrow CH_3$ $\rightarrow CH_2$ $\rightarrow CH$ are $+15, +30$ and $+45 \ kJ \ mol^{-1}$ higher than the mean bond enthalpy of $C-H$ bonds,respectively. The bond enthalpy of the last $C-H$ unit is

Consider the following reactions:
$(i)$ $H_{(aq)}^{+} + OH^{-}_{(aq)} \longrightarrow H_2O_{(l)}$,$\Delta H = -X_1 \ kJ \ mol^{-1}$
$(ii)$ $H_{2_{(g)}} + \frac{1}{2} O_{2_{(g)}} \longrightarrow H_2O_{(l)}$,$\Delta H = -X_2 \ kJ \ mol^{-1}$
$(iii)$ $CO_{2_{(g)}} + H_{2_{(g)}} \longrightarrow CO_{(g)} + H_2O_{(l)}$,$\Delta H = -X_3 \ kJ \ mol^{-1}$
$(iv)$ $C_2H_{2_{(g)}} + \frac{5}{2} O_{2_{(g)}} \longrightarrow 2CO_{2_{(g)}} + H_2O_{(l)}$,$\Delta H = -X_4 \ kJ \ mol^{-1}$
Enthalpy of formation of $H_2O_{(l)}$ is

The bond dissociation enthalpy of $X_2$,$\Delta H_{\text{bond}}^{\circ}$,calculated from the given data is $...$ $kJ \ mol^{-1}$. (Nearest integer)
$M^{+}X^{-}_{(s)} \rightarrow M^{+}_{(g)} + X^{-}_{(g)} \quad \Delta H_{\text{lattice}}^{\circ} = 800 \ kJ \ mol^{-1}$
$M_{(s)} \rightarrow M_{(g)} \quad \Delta H_{\text{sub}}^{\circ} = 100 \ kJ \ mol^{-1}$
$M_{(g)} \rightarrow M^{+}_{(g)} + e^{-}_{(g)} \quad \Delta H_{i}^{\circ} = 500 \ kJ \ mol^{-1}$
$X_{(g)} + e^{-}_{(g)} \rightarrow X^{-}_{(g)} \quad \Delta H_{\text{eg}}^{\circ} = -300 \ kJ \ mol^{-1}$
$M_{(s)} + \frac{1}{2}X_{2(g)} \rightarrow M^{+}X^{-}_{(s)} \quad \Delta H_{f}^{\circ} = -400 \ kJ \ mol^{-1}$
[Given : $M^{+}X^{-}$ is a pure ionic compound and $X$ forms a diatomic molecule $X_2$ in gaseous state]

If $C_{(s)} + O_{2(g)} \longrightarrow CO_{2(g)}; \Delta H = r$ and $CO_{(g)} + \frac{1}{2} O_{2(g)} \longrightarrow CO_{2(g)}; \Delta H = s$,then the heat of formation of $CO$ is

In which of the following neutralisation reactions,the heat of neutralisation will be highest?

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