The standard enthalpy of formation of $H_2O_{(g)}$ at $298 \ K$ is $-241.82 \ kJ \ mol^{-1}$. Calculate the enthalpy of formation of $H_2O_{(g)}$ at $373 \ K$,assuming $C_p$ is independent of temperature.
$C_p$ of $H_2O_{(g)} = 33.58 \ J \ K^{-1} \ mol^{-1}$
$C_p$ of $H_{2(g)} = 28.84 \ J \ K^{-1} \ mol^{-1}$
$C_p$ of $O_{2(g)} = 29.37 \ J \ K^{-1} \ mol^{-1}$
$C_p$ of $H_2O_{(g)} = 33.58 \ J \ K^{-1} \ mol^{-1}$
$C_p$ of $H_{2(g)} = 28.84 \ J \ K^{-1} \ mol^{-1}$
$C_p$ of $O_{2(g)} = 29.37 \ J \ K^{-1} \ mol^{-1}$
- A$-242.6 \ kJ \ mol^{-1}$
- B$+242.6 \ kJ \ mol^{-1}$
- C$+24.26 \ kJ \ mol^{-1}$
- D$-242.6 \ J \ mol^{-1}$
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Calculate the enthalpy change for the process $CCl_{4(g)} \to C_{(g)} + 4Cl_{(g)}$ and calculate the bond enthalpy of the $C-Cl$ bond in $CCl_{4(g)}$.
$\Delta_{vap} H^{\theta}(CCl_{4}) = 30.5 \, kJ \, mol^{-1}$
$\Delta_{f} H^{\theta}(CCl_{4}) = -135.5 \, kJ \, mol^{-1}$
$\Delta_{a} H^{\theta}(C) = 715.0 \, kJ \, mol^{-1}$ (where $\Delta_{a} H^{\theta}$ is enthalpy of atomisation)
$\Delta_{a} H^{\theta}(Cl_{2}) = 242 \, kJ \, mol^{-1}$
$\Delta_{vap} H^{\theta}(CCl_{4}) = 30.5 \, kJ \, mol^{-1}$
$\Delta_{f} H^{\theta}(CCl_{4}) = -135.5 \, kJ \, mol^{-1}$
$\Delta_{a} H^{\theta}(C) = 715.0 \, kJ \, mol^{-1}$ (where $\Delta_{a} H^{\theta}$ is enthalpy of atomisation)
$\Delta_{a} H^{\theta}(Cl_{2}) = 242 \, kJ \, mol^{-1}$
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View SolutionGiven the following thermochemical equations:
$(1) \ S + O_2 \rightarrow SO_2 ; \Delta H = -298.2 \ kJ$
$(2) \ SO_2 + \frac{1}{2} O_2 \rightarrow SO_3 ; \Delta H = -98.7 \ kJ$
$(3) \ SO_3 + H_2O \rightarrow H_2SO_4 ; \Delta H = -130.2 \ kJ$
$(4) \ H_2 + \frac{1}{2} O_2 \rightarrow H_2O ; \Delta H = -287.3 \ kJ$
Calculate the enthalpy of formation of $H_2SO_4$ at $298 \ K$ in $kJ$.
$(1) \ S + O_2 \rightarrow SO_2 ; \Delta H = -298.2 \ kJ$
$(2) \ SO_2 + \frac{1}{2} O_2 \rightarrow SO_3 ; \Delta H = -98.7 \ kJ$
$(3) \ SO_3 + H_2O \rightarrow H_2SO_4 ; \Delta H = -130.2 \ kJ$
$(4) \ H_2 + \frac{1}{2} O_2 \rightarrow H_2O ; \Delta H = -287.3 \ kJ$
Calculate the enthalpy of formation of $H_2SO_4$ at $298 \ K$ in $kJ$.
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View SolutionThe $\Delta H_f^o$ values for $ICl_{(g)}$,$Cl_{(g)}$,and $I_{(g)}$ are $17.57$,$121.34$,and $106.96 \, J \, mol^{-1}$ respectively. What is the bond dissociation energy of the $I-Cl$ bond in $J \, mol^{-1}$?
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View SolutionFor the reaction $2H_2O_2(\ell) \to 2H_2O(\ell) + O_2(g)$,what is the enthalpy change? Given that the heats of formation of $H_2O_2(\ell)$ and $H_2O(\ell)$ are $-188 \, kJ/mol$ and $-286 \, kJ/mol$ respectively.
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