Which of the following substances is insoluble in acetic acid $(CH_3COOH)$?

  • A
    Calcium oxide $(CaO)$
  • B
    Calcium carbonate $(CaCO_3)$
  • C
    Calcium oxalate $(CaC_2O_4)$
  • D
    Calcium hydroxide $(Ca(OH)_2)$

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Consider two Group $IV$ metal ions $X^{2+}$ and $Y^{2+}$. $A$ solution containing $0.01 \ M$ $X^{2+}$ and $0.01 \ M$ $Y^{2+}$ is saturated with $H_2S$. The pH at which the metal sulphide $YS$ will form as a precipitate is . . . . . . (Nearest integer). (Given: $K_{sp}(XS)=1 \times 10^{-22}$ at $25^{\circ} C$, $K_{sp}(YS)=4 \times 10^{-16}$ at $25^{\circ} C$, $[H_2S]=0.1 \ M$ in solution, $K_{a1} \times K_{a2}(H_2S)=1.0 \times 10^{-21}$, $\log 2=0.30, \log 3=0.48, \log 5=0.70$)

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