Which of the following mixtures represents Proof Spirit (by volume)?

At $T(K)$, $2$ moles of liquid $A$ and $3$ moles of liquid $B$ are mixed. The vapour pressure of the ideal solution formed is $320 \ mm \ Hg$. At this stage, one mole of $A$ and one mole of $B$ are added to the solution. The vapour pressure is now measured as $328.6 \ mm \ Hg$. The vapour pressures of pure $A$ and pure $B$ (in $mm \ Hg$) are respectively:

Which of the following statements concerning the properties of solutions describes a colligative effect?

Assertion : If one component of a solution obeys Raoult's law over a certain range of composition,the other component will not obey Henry's law in that range.
Reason : Raoult's law is a special case of Henry's law.

For $0.1 \ M$ solutions of urea and $Al_2(SO_4)_3$,which of the following statements is correct? $(a)$ $i$ for urea is $1$ and $i$ for $Al_2(SO_4)_3$ is $5$. $(b)$ $Al_2(SO_4)_3$ has a higher elevation in boiling point. $(c)$ $Al_2(SO_4)_3$ has a higher depression in freezing point. $(d)$ Urea has a higher vapor pressure.

$2.5 \ g$ of a non-volatile,non-electrolyte is dissolved in $100 \ g$ of water at $25^{\circ} C$. The solution showed a boiling point elevation by $2^{\circ} C$. Assuming the solute concentration is negligible with respect to the solvent concentration,the vapour pressure of the resulting aqueous solution is . . . . . . $mm$ of $Hg$ (nearest integer).
[Given : Molal boiling point elevation constant of water $(K_b) = 0.52 \ K \ kg \ mol^{-1}$,
$1 \ atm$ pressure $= 760 \ mm$ of $Hg$,molar mass of water $= 18 \ g \ mol^{-1}]$