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(D) The synthesis of ethers via the Williamson ether synthesis involves the reaction of an alkoxide ion with an alkyl halide. To synthesize methyl ter

Vedclass · Accepted Answer

$(CH_3)_3C-ONa + CH_3Cl$

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(D) The synthesis of ethers via the Williamson ether synthesis involves the reaction of an alkoxide ion with an alkyl halide. To synthesize methyl tert-butyl ether,$(CH_3)_3C-O-CH_3$,we must choose reactants that avoid the elimination reaction. Tertiary alkyl halides undergo $E2$ elimination in the presence of strong bases (alkoxides). Therefore,we must use a tertiary alkoxide and a primary alkyl halide. Reaction: $(CH_3)_3C-ONa + CH_3Cl \rightarrow (CH_3)_3C-O-CH_3 + NaCl$. This corresponds to option $D$.

Which of the following reactions will produce methyl tert-butyl ether?

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