If the $\Delta H_{fusion}$ of a substance is $'x'$ and $\Delta H_{vap}$ is $'y'$,then $\Delta H_{sublimation}$ will be:

  • A
    $x + y$
  • B
    $x - y$
  • C
    $x / y$
  • D
    $y / x$

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State and prove Hess's law of constant heat summation.

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The enthalpy of solution of $BaCl_{2(s)}$ and $BaCl_2 \cdot 2H_2O_{(s)}$ are $-20.6 \, kJ \, mol^{-1}$ and $8.8 \, kJ \, mol^{-1}$ respectively. The enthalpy change for the reaction $BaCl_{2(s)} + 2H_2O_{(l)} \to BaCl_2 \cdot 2H_2O_{(s)}$ is $...... \, kJ \, mol^{-1}$.

The standard enthalpies of combustion of $C_6H_{6(l)}$,$C(graphite)$ and $H_{2(g)}$ are respectively $-3270 \ kJ \ mol^{-1}$,$-394 \ kJ \ mol^{-1}$ and $-286 \ kJ \ mol^{-1}$. What is the standard enthalpy of formation of $C_6H_{6(l)}$ in $kJ \ mol^{-1}$?

The standard heats of formation for $CH_4$, $C_2H_4$, and $C_3H_8$ are $-17.9$, $12.5$, and $-24.8 \ kcal/mol$ respectively. The heat of reaction $(\Delta H)$ for the reaction $CH_4 + C_2H_4 \rightarrow C_3H_8$ in $kcal$ is:

The $\Delta H_f^o$ values for $ICl_{(g)}$,$Cl_{(g)}$,and $I_{(g)}$ are $17.57$,$121.34$,and $106.96 \, J \, mol^{-1}$ respectively. What is the bond dissociation energy of the $I-Cl$ bond in $J \, mol^{-1}$?

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