$3.00 \, mol$ of $PCl_5$ kept in $1 \, L$ closed reaction vessel was allowed to attain equilibrium at $380 \, K$. Calculate the composition of the mixture at equilibrium. Given $K_c = 1.80$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The equilibrium reaction is: $PCl_5(g) \rightleftharpoons PCl_3(g) + Cl_2(g)$
Initial concentrations: $[PCl_5] = 3.0 \, M$,$[PCl_3] = 0 \, M$,$[Cl_2] = 0 \, M$
Let $x \, mol/L$ be the amount of $PCl_5$ dissociated at equilibrium.
Equilibrium concentrations: $[PCl_5] = (3.0 - x) \, M$,$[PCl_3] = x \, M$,$[Cl_2] = x \, M$
The equilibrium constant expression is: $K_c = \frac{[PCl_3][Cl_2]}{[PCl_5]}$
Substituting the values: $1.8 = \frac{x^2}{3.0 - x}$
Rearranging into a quadratic equation: $x^2 + 1.8x - 5.4 = 0$
Using the quadratic formula $x = \frac{-b \pm \sqrt{b^2 - 4ac}}{2a}$:
$x = \frac{-1.8 \pm \sqrt{(1.8)^2 - 4(1)(-5.4)}}{2(1)}$
$x = \frac{-1.8 \pm \sqrt{3.24 + 21.6}}{2} = \frac{-1.8 \pm \sqrt{24.84}}{2} \approx \frac{-1.8 \pm 4.98}{2}$
Since $x$ must be positive: $x = \frac{3.18}{2} = 1.59 \, M$
Equilibrium composition:
$[PCl_5] = 3.0 - 1.59 = 1.41 \, M$
$[PCl_3] = 1.59 \, M$
$[Cl_2] = 1.59 \, M$

Explore More

Similar Questions

Consider the reaction,$P(aq) \rightleftharpoons Q(aq)$ with an equilibrium constant $K=1.5$. The reaction is started in a vessel with a concentration of $[P]$ of $2 \ M$ and concentration of $[Q]=0$. When the equilibrium is established,half the amount of $P$ is removed,and the reaction is allowed to re-equilibrate. The concentration of $Q$ in the vessel (in $M$) is closest to

In a $10 \ L$ vessel,$1 \ mol$ each of $PCl_5$ and $PCl_3$ are present. If the vessel is heated,some $PCl_5$ dissociates. What are the concentrations of $PCl_5$,$PCl_3$,and $Cl_2$ at equilibrium,respectively?

Difficult
View Solution

Air containing $79\%$ of nitrogen and $21\%$ of oxygen by volume is heated at $2200 \ K$ and $1 \ atm$ until equilibrium is established according to the reaction $N_{2(g)} + O_{2(g)} \rightleftharpoons 2NO_{(g)}$. If the $K_p$ of the reaction is $1.1 \times 10^{-3}$,calculate the amount of nitric oxide produced in terms of volume percent.

The equilibrium composition for the reaction $PCl_3 + Cl_2 \rightleftharpoons PCl_5$ at $298 \, K$ is given below.
$[PCl_3]_{eq} = 0.2 \, mol \, L^{-1}$
$[Cl_2]_{eq} = 0.1 \, mol \, L^{-1}$
$[PCl_5]_{eq} = 0.40 \, mol \, L^{-1}$
If $0.2 \, mol$ of $Cl_2$ is added at the same temperature,the equilibrium concentration of $PCl_5$ is $.... \times 10^{-2} \, mol \, L^{-1}$. Given: $K_c$ for the reaction at $298 \, K$ is $20$.

$5 \ \text{moles}$ of $SO_2$ and $5 \ \text{moles}$ of $O_2$ are allowed to react to form $SO_3$ in a closed vessel. At the equilibrium stage,$60\%$ of $SO_2$ is used up. The total number of moles of $SO_2$,$O_2$,and $SO_3$ in the vessel now is:

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo