Fill in the blanks:
$(i)$ The enthalpy change that occurs when one mole of a compound is formed from its constituent elements in their standard states is called the ...... of that compound.
$(ii)$ The total heat change in a chemical reaction is equal to the algebraic sum of the heat changes of the individual steps of the reaction. This law was given by ............. .
$(iii)$ $A$ process during which there is no exchange of heat between the system and the surroundings is called an ................ process.
$(iv)$ The standard enthalpy value of any element in its standard state is considered to be ...... .

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(N/A) $(i)$ Standard enthalpy of formation
$(ii)$ Hess's Law
$(iii)$ Adiabatic
$(iv)$ Zero

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Calculate the enthalpy of formation of ethylene $(C_2H_4)$ from the following data:
$(I)$ $C_{\text{(graphite)}} + O_{2(g)} \longrightarrow CO_{2(g)}$; $\Delta H = -393.5 \ kJ$
$(II)$ $H_{2(g)} + \frac{1}{2} O_{2(g)} \longrightarrow H_2O_{(l)}$; $\Delta U = -256.2 \ kJ$
$(III)$ $C_2H_{4(g)} + 3 O_{2(g)} \longrightarrow 2 CO_{2(g)} + 2 H_2O_{(l)}$; $\Delta H = -1410.8 \ kJ$ (in $kJ$)

Consider the following data:
$(i)$ $2Al(s) + 6HCl(aq) \to Al_2Cl_6(aq) + 3H_2(g) + 1200 \text{ kJ/mol}$
(ii) $H_2(g) + Cl_2(g) \to 2HCl(g) + 164 \text{ kJ/mol}$
(iii) $HCl(g) + aq \to HCl(aq) + 83 \text{ kJ/mol}$
(iv) $Al_2Cl_6(s) + aq \to Al_2Cl_6(aq) + 663 \text{ kJ/mol}$
The enthalpy of formation of anhydrous solid $Al_2Cl_6$ is:

The heat of neutralization of four acids $A$,$B$,$C$,and $D$ are $-13.0$,$-12.6$,$-9.2$,and $-11.7 \ KCal/eq$ respectively when neutralized by $NaOH$. The order of acidic strength of the four acids will be:

What will be the $C-H$ bond enthalpy if:
$CH_{4(g)} + 2O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O_{(l)};$ $\Delta H = -890 \, kJ$
$CO_{2(g)} \rightarrow C_{(graphite)} + O_{2(g)};$ $\Delta H = 393 \, kJ$
$2H_2O_{(l)} \rightarrow 2H_{2(g)} + O_{2(g)};$ $\Delta H = 571 \, kJ$
$2H_{2(g)} \rightarrow 4H_{(g)};$ $\Delta H = 871 \, kJ$
$C_{(graphite)} \rightarrow C_{(g)};$ $\Delta H = 716 \, kJ$

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The standard enthalpy of formation of $NH_3$ is $-46.0 \ kJ \ mol^{-1}.$ If the enthalpy of formation of $H_2$ from its atoms is $-436 \ kJ \ mol^{-1}$ and that of $N_2$ is $-712 \ kJ \ mol^{-1},$ the average bond enthalpy of $N-H$ bond in $NH_3$ is ................ $kJ \ mol^{-1}$

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