In the reaction shown below,the structural formula of $(A)$,$X$ and $Y$ respectively are:
$C_7H_7N_2OCl + C_2H_5OH \rightarrow \text{Anisole} + N_2 + X + Y$

  • A
    $p-\text{methoxyphenyl diazonium chloride}, CH_3CHO, HCl$
  • B
    $p-\text{methoxyphenyl diazonium chloride}, \text{ethylene oxide}, HCl$
  • C
    $p-\text{methoxyphenyl diazonium chloride}, CH_3CHO, H_2O$
  • D
    $p-\text{methoxyphenyl diazonium chloride}, \text{ethylene oxide}, H_2O$

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Match the reactions in Column-$I$ with their mechanisms in Column-$II$.
Column-$I$ (Reaction) Column-$II$ (Mechanism)
$(A)$ $OH^- + CH_3Cl \to HOCH_3 + Cl^-$ $(1)$ $S_N2$ mechanism
$(B)$ $(CH_3)_3CBr + OH^- \to (CH_3)_3COH + Br^-$ $(2)$ $S_E2$ aromatic
$(C)$ $CH_3CH_2Br \xrightarrow[ethanol]{KOH} CH_2 = CH_2$ $(3)$ $S_N1$ mechanism
$(D)$ $C_6H_6 + Br_2 \xrightarrow{Fe} C_6H_5Br + HBr$ $(4)$ $\beta$-elimination (dehydrohalogenation)

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Match the reactions in Column-$A$ with the products in Column-$B$ and select the correct option:
Column-$A$Column-$B$
$(1)$ $CH_3-CH_2-Cl + KOH_{(aq)} \rightarrow$$(A)$ $1,2-\text{dichloroethane}$
$(2)$ $CH_3-CH_2-CH_2-CH_3 \xrightarrow{AlCl_3/HCl}$$(B)$ $\text{Chloromethane}$
$(3)$ $CH_3-CH_2-Br + \text{alc. } KOH \rightarrow$$(C)$ $\text{But-2-ene}$
$(4)$ $CH_2=CH_2 + Cl_2 \rightarrow$$(D)$ $\text{Ethanol}$
$(E)$ $\text{Chloroethane}$
$(F)$ $\text{Ethene}$
$(G)$ $\text{Isobutane}$

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Which of the following compounds is a tertiary alkyl halide?

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The total number of monohalogenated organic products (including stereoisomers) formed in the following reaction is:
$A$ (simplest optically active alkene) $\xrightarrow[(ii) X_2/\Delta ]{(i) H_2/Ni/\Delta }$

Product $A$ is

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