$A$ buffer solution of $pH = 9.80$ is to be prepared from $1 \ M \ NH_4Cl$ and $1 \ M \ NH_3$ solution. $pK_{b}$ of $NH_3$ is $4.74$. In $1 \ L$ of the buffer solution,the volume of $NH_4Cl$ solution required is $(\log 0.28 = -0.54) :-$ (in $mL$)

$A$ litre of buffer solution contains $0.1 \ mol$ of each of $NH_3$ and $NH_4Cl$. On the addition of $0.02 \ mol$ of $HCl$ by dissolving gaseous $HCl$,the $pH$ of the solution is found to be $...... \times 10^{-3}$ (Nearest integer).
Given: $pK_b(NH_3) = 4.745$,$\log 2 = 0.301$,$\log 3 = 0.477$,$T = 298 \ K$.

Which of the following mixtures in water acts as a buffer?

$50 \ mL$ of $2 \ N$ acetic acid mixed with $10 \ mL$ of $1 \ N$ sodium acetate solution will have an approximate $pH$ of:

$50 \, mL$ of $0.1 \, M \, CH_3COOH$ is being titrated against $0.1 \, M \, NaOH$. When $25 \, mL$ of $NaOH$ has been added,the $pH$ of the solution will be $.... \times 10^{-2}$. (Nearest integer)
(Given : $pK_a(CH_3COOH) = 4.76$)
$\log 2 = 0.30$,$\log 3 = 0.48$,$\log 5 = 0.69$,$\log 7 = 0.84$,$\log 11 = 1.04$

$A$ solution of $0.1 \ mol$ of $CH_3NH_2$ $(K_b = 5 \times 10^{-4})$ and $0.08 \ mol$ of $HCl$ is diluted to $1 \ L$. The $pOH$ of the resulting solution is $(\log 1.25 = 0.1)$.