Cl-CH_2-COONa on boiling with aqueous sodium | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(A) The reaction of sodium $\alpha$-chloroacetate with aqueous sodium nitrite involves the substitution of the chlorine atom by the nitro group,follow

Vedclass · Accepted Answer

Nitromethane

Vedclass · Answer

(A) The reaction of sodium $\alpha$-chloroacetate with aqueous sodium nitrite involves the substitution of the chlorine atom by the nitro group,followed by decarboxylation upon boiling with water.The reaction proceeds as follows:$Cl-CH_2-COONa + NaNO_2 \rightarrow O_2N-CH_2-COONa + NaCl$Then,the intermediate $O_2N-CH_2-COONa$ undergoes decarboxylation in the presence of water:$O_2N-CH_2-COONa + H_2O \rightarrow CH_3NO_2 + NaHCO_3$Thus,the final product is nitromethane $(CH_3NO_2)$.

$Cl-CH_2-COONa$ on boiling with aqueous sodium nitrite gives:

Similar Questions

In a set of reactions,$m$-bromobenzoic acid gives a product $D$. Identify the product $D$.

Which of the following amines is obtained by Gabriel phthalimide synthesis?

The conversion of $C_6H_5CONHCH_3$ to $C_6H_5CH_2NHCH_3$ can be carried out by using:

Gabriel phthalamide synthesis is used for the preparation of :-

In the preparation of a $1^{\circ}$-amine from an alkyl halide,with simultaneous addition of one $-CH_2-$ group to the carbon chain,the reagent used as the source of nitrogen is

Vedclass Test Series

Exam Paper Generator

Online Exam Module