$A$ purple colored compound of Manganese $(X)$ decomposes on heating to liberate oxygen and forms compounds of Manganese $(Y)$ and $(Z)$. Compound $(Z)$ reacts with $KOH$ in the presence of potassium nitrate to give compound $(Y)$. Compounds $(X)$,$(Y)$,and $(Z)$ respectively are:

  • A
    $X = KMnO_4, Y = Mn_2O_7, Z = MnO_2$
  • B
    $X = K_2MnO_4, Y = KMnO_4, Z = Mn_2O_7$
  • C
    $X = KMnO_4, Y = K_2MnO_4, Z = MnO_2$
  • D
    $X = KMnO_4, Y = MnO_2, Z = MnO$

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$KMnO_4$ decomposes on heating at $513 \ K$ to form $O_2$ along with

$X + KOH + O_2 \to Y + H_2O$,
$Y + H_2SO_4 \to Z + K_2SO_4 + MnO_2 + H_2O$
Identify $X, Y$ and $Z$ in the above reactions.

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Sodium chromate,$Na_2CrO_4$ is made commercially by

Assertion : Coloured cations can be identified by borax bead test.
Reason : Transparent bead $(NaBO_2 + B_2O_3)$ forms coloured bead with coloured cation.

Which of the following statements are $INCORRECT$?
$A$. All the transition metals except scandium form $MO$ oxides which are ionic.
$B$. The highest oxidation number corresponding to the group number in transition metal oxides is attained in $Sc_2O_3$ to $Mn_2O_7$.
$C$. Basic character increases from $V_2O_3$ to $V_2O_4$ to $V_2O_5$.
$D$. $V_2O_4$ dissolves in acids to give $VO_4^{3-}$ salts.
$E$. $CrO$ is basic but $Cr_2O_3$ is amphoteric.
Choose the correct answer from the options given below:

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