For the reaction $Br_{2(l)} + Cl_{2(g)} \rightarrow 2BrCl_{(g)}$,the enthalpy change is $\Delta H = 30 \ kJ/mol$ and the entropy change is $\Delta S = 105 \ J/mol \cdot K$. The temperature at equilibrium is $...... \ K$.

  • A
    $450$
  • B
    $300$
  • C
    $285.7$
  • D
    $273$

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Consider the following data for the reaction $X_2(g) + Y_2(g) \rightleftharpoons 2XY(g)$ at $600 \ K$. The $\Delta_r G^\circ$ (in $kJ \ mol^{-1}$) for the reaction is:
Compound $\Delta_f H^\circ$ $(kJ \ mol^{-1})$ $S^\circ$ $(J \ mol^{-1} \ K^{-1})$
$XY(g)$ $42$ $200$
$X_2(g)$ $8$ $140$
$Y_2(g)$ $80$ $250$

Which of the following relations are correct?
$(A)$ $\Delta U = q + p \Delta V$
$(B)$ $\Delta G = \Delta H - T \Delta S$
$(C)$ $\Delta S = \frac{q_{rev}}{T}$
$(D)$ $\Delta H = \Delta U - \Delta nRT$
Choose the most appropriate answer from the options given below:

$A$ solution of $500 \ mL$ of $2 \ M \ KOH$ is added to $500 \ mL$ of $2 \ M \ HCl$ and the mixture is well shaken. The rise in temperature $T_1$ is noted. The experiment is then repeated using $250 \ mL$ of each solution and the rise in temperature $T_2$ is again noted. Assume all heat is absorbed by the solution.

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The reaction of cyanamide,$NH_2CN_{(s)}$,with dioxygen was carried out in a bomb calorimeter,and $\Delta U$ was found to be $-742.7 \ kJ \ mol^{-1}$ at $298 \ K$. Calculate the enthalpy change for the reaction at $298 \ K$.
$NH_2CN_{(s)} + \frac{3}{2}O_{2_{(g)}} \to N_{2_{(g)}} + CO_{2_{(g)}} + H_2O_{(l)}$

The number of endothermic process/es from the following is:
$A. I_{2(g)} \rightarrow 2I_{(g)}$
$B. HCl_{(g)} \rightarrow H_{(g)} + Cl_{(g)}$
$C. H_2O_{(l)} \rightarrow H_2O_{(g)}$
$D. C_{(s)} + O_{2(g)} \rightarrow CO_{2(g)}$
$E. \text{Dissolution of ammonium chloride in water}$

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