The relation $q = -w$ is $NOT$ true for which of the following processes?

The gas absorbs $100 \ J$ and is simultaneously compressed by a constant external pressure of $1.50 \ atm$ from $8 \ L$ to $2 \ L$ volume. Hence $\Delta U$ will be ..... $J$.

Five moles of an ideal gas at $293 \, K$ is expanded isothermally from an initial pressure of $2.1 \, MPa$ to $1.3 \, MPa$ against a constant external pressure of $4.3 \, MPa$. The heat transferred in this process is $...... \, kJ \, mol^{-1}$. (Rounded-off to the nearest integer) $\left[\right.$ Use $R = 8.314 \, J \, mol^{-1} \, K^{-1}\left.\right]$

Which of the following is the correct expression of the first law of thermodynamics for adiabatic processes?

Which of the following processes exhibits an increase in internal energy?

The correct relationship is