When $50 \ g$ of iron is dissolved in $HCl$ at $25 \ ^\circ C$ in a closed vessel,the work done is calculated to be ..... . The atmospheric pressure is $1 \ atm$. (in $J$)

Fill in the blanks given below:
$(i)$ $A$ system in which the exchange of energy between the system and the surroundings is possible but the exchange of matter is not possible is called a .......
$(ii)$ The total amount of energy, which is the sum of the internal energy of the substance and the product of its pressure and volume, is called .......
$(iii)$ The change in energy that occurs when a chemical reaction is carried out at constant pressure is called .......
$(iv)$ The process of attaining thermal equilibrium between any two heat-conducting substances is known as the ....... law of thermodynamics.

The heat of combustion of ethanol in a bomb calorimeter at $25\,^oC$ is $-670.48\, K\,cal\, mol^{-1}$. Find the value of $\Delta U$ in $K\,cal$ for the reaction at $25\,^oC$.

Calculate work done in isothermal reversible expansion of $1 \ mol$ of an ideal gas from an initial pressure of $10 \ bar$ to a final pressure of $1 \ bar$ at $300 \ K$ $\left(R = 8.314 \ J \ K^{-1} \ mol^{-1}\right)$. (in $kJ$)

Which of the following is not an extensive property?

At $27\,^{\circ}C$,$1\, mole$ of an ideal gas expands reversibly and isothermally from $2\, atm$ to $1\, atm$. Then $\Delta H$ will be......$kJ$.