The standard enthalpy of formation $(\Delta_fH^o)$ of methane $(CH_{4(g)})$ at $298 \, K$ is $-74.8 \, kJ \, mol^{-1}$. What additional information is required to calculate the average bond energy of the $C-H$ bond?

  • A
    Latent heat of vaporization of methane
  • B
    First four ionization energies of carbon and electron gain enthalpy of hydrogen
  • C
    Dissociation energy of hydrogen molecule $(H_2)$
  • D
    Dissociation energy of $H_2$ and enthalpy of sublimation of carbon

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Given:
$(I) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)}; \Delta H^o_{298\ K} = -285.9 \ kJ \ mol^{-1}$
$(II) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(g)}; \Delta H^o_{298\ K} = -241.8 \ kJ \ mol^{-1}$
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The enthalpies of combustion of $C$(graphite) and $C$(diamond) are $-393.8 \ kJ \ mol^{-1}$ and $-395.3 \ kJ \ mol^{-1}$ respectively. The enthalpy of conversion of $C$(graphite) to $C$(diamond) is

What is the quantity of heat evolved when $6 \ g$ of carbon combines with sulphur to form $CS_2$ according to the reaction $C + 2S \rightarrow CS_2 \quad \Delta H = 92 \ kJ \ mol^{-1}$ (in $kJ$)?

Energy required to dissociate $16 \ g$ of oxygen gas $(O_2)$ into free atoms is $x \ kJ$. The heat of atomisation of oxygen is:

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