Which ion produces a brown gas when the mixture is heated with $MnO_2$ and concentrated $H_2SO_4$?

$A$ white sodium salt dissolves readily in water to give a solution which is neutral to litmus. When silver nitrate solution is added to the aforementioned solution,a white precipitate is obtained which does not dissolve in dilute nitric acid. The anion is:

$[X] +$ dil. $H_{2}SO_{4} \longrightarrow [Y]:$
Colourless, suffocating gas
$[Y] + K_{2}Cr_{2}O_{7} + H_{2}SO_{4} \longrightarrow$
Green colouration of solution
Then, $[X]$ and $[Y]$ are

In the chromyl chloride test,the reagent used is

The reagent$(s)$ that can selectively precipitate $S^{2-}$ from a mixture of $S^{2-}$ and $SO_4^{2-}$ in aqueous solution is(are):
$(A)$ $CuCl_2$
$(B)$ $BaCl_2$
$(C)$ $Pb(CH_3COO)_2$
$(D)$ $Na_2[Fe(CN)_5NO]$

$A$ substance reacts with dilute $H_2SO_4$ to release a colorless gas which $(i)$ turns baryta water turbid and $(ii)$ turns acidic dichromate solution green. This reaction indicates the presence of which of the following?