In which of the following reactions will a change in pressure not affect the rate of reaction?

  • A
    $PCl_3(g) + Cl_2(g) \rightleftharpoons PCl_5(g)$
  • B
    $N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$
  • C
    $N_2(g) + O_2(g) \rightleftharpoons 2NO(g)$
  • D
    $2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g)$

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At $25 \ ^oC$,the reaction $SO_2Cl_2(g) \rightleftharpoons SO_2(g) + Cl_2(g)$ is in equilibrium in a closed vessel. If an inert gas,$He$,is added to this system at constant volume,which of the following statements is true?

In which of the following reactions does the yield of the product not increase by the application of high pressure?

For the chemical reaction: $BaO_{2(s)} \rightleftharpoons BaO_{(s)} + \frac{1}{2} O_{2(g)}$,$\Delta H = +ve$. At equilibrium,the pressure of $O_2$ depends upon:

The exothermic formation of $ClF_3$ is represented by the equation $Cl_{2(g)} + 3F_{2(g)} \rightleftharpoons 2ClF_{3(g)}$; $\Delta H = -329 \ kJ$. Which of the following will increase the quantity of $ClF_3$ in an equilibrium mixture of $Cl_2, F_2$ and $ClF_3$?

When $I_2$ dissociates to its atomic form the following reaction occurs:
$I_{2(g)} \rightleftharpoons 2I_{(g)} ; \Delta_r H^o = +150 \ kJ \ mol^{-1}$
The forward reaction is favoured at:

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