Which of the following represents the correct solubility product expression for calcium phosphate?

  • A
    $[Ca^{2+}] [PO_4^{3-}]$
  • B
    $[Ca^{2+}] [PO_4^{3-}]^2$
  • C
    $[Ca^{2+}]^3 [PO_4^{3-}]^2$
  • D
    $[Ca^{2+}]^2 [PO_4^{3-}]^2$

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An aqueous solution contains $SCN^{-}$,$Br^{-}$,$I^{-}$,and $Cl^{-}$ ions. When $AgNO_3$ is added to the solution,which of these will precipitate first? Given: $K_{sp}(AgCl) = 1.2 \times 10^{-10}$,$K_{sp}(AgI) = 1.7 \times 10^{-16}$,$K_{sp}(AgSCN) = 7.1 \times 10^{-7}$,$K_{sp}(AgBr) = 3.5 \times 10^{-13}$.

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Find the solubility in terms of $mol \ L^{-1}$ if the solubility product of silver bromide is $6.4 \times 10^{-13}$.

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