$A$ buffer solution can be prepared by mixing which of the following?

Which of the following mixtures will have the lowest $pH$ at $298 \ K$?

$A$ buffer solution is prepared by mixing $0.2 \ M \ NH_4OH$ and $1 \ M \ NH_4Cl$. What is the $pH$ value of the buffer solution? (Given $pK_b = 4.744$)

The $pH$ of blood is maintained by a proper balance of $H_2CO_3$ and $NaHCO_3$ concentrations. What volume of $5 \, M \, NaHCO_3$ solution should be mixed with $10 \, mL$ of $2 \, M \, H_2CO_3$ to maintain a $pH$ of $7.4$ (in $, mL$)? (Given: $K_a$ for $H_2CO_3 = 7.8 \times 10^{-7}$)

Find the $pH$ when $0.2 \, mol$ of $HCl$ is added to $1 \, L$ of a solution containing $1 \, M$ $CH_3COOH$ and $1 \, M$ $CH_3COO^-$. Assume the total volume remains $1 \, L$. Given $K_a$ for $CH_3COOH = 1.8 \times 10^{-5}$.

$A$ buffer solution is formed by a weak acid and its salt with a strong base,or a weak base and its salt with a strong acid. In which of the following pairs is this characteristic found?