Which of the following solutions does not act as a buffer?

$A$ buffer solution is prepared by mixing $0.01 \ M$ $HCN$ and $0.02 \ M$ $NaCN$. If $K_{a}$ for $HCN$ is $6.6 \times 10^{-10}$,what is the concentration of $H^{+}$ ions in the solution?

The $pH$ of a buffer solution made by mixing $25 \ mL$ of $0.02 \ M$ $NH_4OH$ and $25 \ mL$ of $0.2 \ M$ $NH_4Cl$ at $25^{\circ}C$ is ($pK_b$ of $NH_4OH = 4.8$).

$A$ buffer solution contains $100 \ mL$ of $0.01 \ M \ CH_3COOH$ and $200 \ mL$ of $0.02 \ M \ CH_3COONa$. If $700 \ mL$ of $1 \ M \ NaCl$ is added,what are the $pH$ values before and after the addition? $(pK_a = 4.74)$

Derive the equation for the calculation of $pH$ of an acidic buffer solution.

Which of the following mixtures forms an acidic buffer?