Which aqueous solution has the lowest freezing point?

What is the mass of solute having molar mass $60 \ g \ mol^{-1}$ when dissolved in $98 \ g$ of solvent decreases its freezing point by $0.2 \ K$ (in $g$)? (The numerical value of cryoscopic constant of solvent is $1.71 \ K \ kg \ mol^{-1}$)

$A$ solution containing $62 \ g$ of ethylene glycol in $250 \ g$ of water is cooled to $-10 \ ^\circ C$. If $K_f$ for water is $1.86 \ K \ kg \ mol^{-1}$,the amount of water (in $g$) separated as ice is:

For $1000 \ g$ of $1,4$-dioxane,the cryoscopic constant $K_f = 4.9 \ K \ kg \ mol^{-1}$. What will be the depression in freezing point for a $0.001 \ m$ solution prepared in dioxane?

How much glucose $(molecular \ weight = 180 \ g/mol)$ should be added to $200 \ g \ H_2O$ so that when the solution is cooled to $-0.5^{\circ}C$,$14 \ g$ of ice separates out of the solution: [$K_f = 1.86 \ K \ kg/mol$ and melting point of $H_2O = 0^{\circ}C$] (in $g$)

The freezing point depression of a solution containing $0.6 \ g$ of urea (molar mass $= 60 \ g \ mol^{-1}$) in $100 \ mL$ of benzene (in $K$) is ($K_f$ of benzene $= 4.0 \ K \ kg \ mol^{-1}$).