In which of the following production processes is limestone $(CaCO_3)$ $NOT$ used?

The extraction of aluminum from its oxide $(Al_2O_3)$ is done by:

Tin is obtained from cassiterite by reduction with coke. Use the data given below to determine the minimum temperature (in $K$) at which the reduction of cassiterite by coke would take place.
At $298 \ K$: $\Delta_{f}H^{\circ}(SnO_{2(s)}) = -581.0 \ kJ \ mol^{-1}$,$\Delta_{f}H^{\circ}(CO_{2(g)}) = -394.0 \ kJ \ mol^{-1}$
$S^{\circ}(SnO_{2(s)}) = 56.0 \ J \ K^{-1} \ mol^{-1}$,$S^{\circ}(Sn_{(s)}) = 52.0 \ J \ K^{-1} \ mol^{-1}$
$S^{\circ}(C_{(s)}) = 6.0 \ J \ K^{-1} \ mol^{-1}$,$S^{\circ}(CO_{2(g)}) = 210.0 \ J \ K^{-1} \ mol^{-1}$
Assume that the enthalpies and the entropies are temperature independent.

The metal which is extracted by oxidation and subsequent reduction from its ore is:

Bessemerization is used in the extraction of

Among the following,the main reactions occurring in the blast furnace during the extraction of iron from haematite are:
$i$. $Fe_2O_3 + 3CO \rightarrow 2Fe + 3CO_2$
$ii$. $FeO + SiO_2 \rightarrow FeSiO_3$
$iii$. $Fe_2O_3 + 3C \rightarrow 2Fe + 3CO$
$iv$. $CaO + SiO_2 \rightarrow CaSiO_3$