What is the product formed when propene react | vedclass

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(B) The reaction of propene $(CH_3-CH=CH_2)$ with $HCl$ follows the Markovnikov addition rule. Peroxide effect (Kharasch effect) is only applicable to

Vedclass · Accepted Answer

$2$-chloropropane

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(B) The reaction of propene $(CH_3-CH=CH_2)$ with $HCl$ follows the Markovnikov addition rule. Peroxide effect (Kharasch effect) is only applicable to $HBr$ and not to $HCl$ or $HI$. Therefore,the addition of $HCl$ to propene in the presence of peroxide still follows the Markovnikov rule,where the $Cl^-$ ion attaches to the more substituted carbon atom. Thus,the major product is $2$-chloropropane $(CH_3-CHCl-CH_3)$.

What is the product formed when propene reacts with $HCl$ in the presence of peroxide?

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