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Which one of the following has the smallest heat of combustion?

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The reaction $\text{spiro[3.3]hept-1-ene} \xrightarrow{H^+, \Delta} A$. The product $A$ is:

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Identify the total number of compounds containing at least one chiral carbon atom from the following list:
$1$. $2-$methylcyclohexanone
$2$. Cyclopentane$-1,3-$dione
$3$. $CH_3-CH_2-CH(NO_2)-COOH$
$4$. $CH_3-CH(I)-CH_2-NO_2$
$5$. $CH_3-CH_2-CH(OH)-CH_2OH$
$6$. $CH_3-CH_2-CH(I)-C_2H_5$

What is the relationship between the two structures shown?

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Among the following,the most stable isomer is

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