The complexes [CO(NO_2)(NH_3)_5]Cl_2 and [CO( | vedclass

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(D) The given complexes contain the ambidentate ligand $NO_2^-$. An ambidentate ligand is a ligand that can coordinate to the central metal atom throu

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Linkage isomerism

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(D) The given complexes contain the ambidentate ligand $NO_2^-$. An ambidentate ligand is a ligand that can coordinate to the central metal atom through two different atoms. In $[CO(NO_2)(NH_3)_5]Cl_2$,the $NO_2$ group is bonded through the nitrogen atom (nitro). In $[CO(ONO)(NH_3)_5]Cl_2$,the $NO_2$ group is bonded through the oxygen atom (nitrito). This type of isomerism,where the ligand coordinates through different donor atoms,is known as linkage isomerism.

The complexes $[CO(NO_2)(NH_3)_5]Cl_2$ and $[CO(ONO)(NH_3)_5]Cl_2$ are examples of .....

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