$A$ liquid with a high boiling point decomposes on simple distillation,but it can be steam distilled for its purification. Explain how this is possible.

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(N/A) In steam distillation,the vapour of the organic compound and water are distilled out. Steam (water vapour) is passed into the liquid that is to be purified.
Consequently,the vapour of the liquid and the vapour of water rise and pass into the condenser. The liquid and water are immiscible and form separate layers.
When the sum of the partial vapour pressures of the liquid $(p_1)$ and water $(p_2)$ becomes equal to the atmospheric pressure $(p)$,distillation takes place.
Mathematically,$p = p_1 + p_2$. Since $p_1 < p$,the liquid distills at a temperature lower than its normal boiling point.
Therefore,steam distillation takes place at a lower temperature than the boiling point of the organic liquid,preventing thermal decomposition.

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Explain the process of fractional distillation.

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In chromatography technique,the purification of a compound is independent of:

The correct match between items of List-$I$ and List-$II$ is
List-$I$ List-$II$
$A$. Coloured impurity $(p)$. Steam distillation
$B$. Mixture of $o-$nitrophenol and $p-$nitrophenol $(q)$. Fractional distillation
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$D$. Mixture of glycerol and sugars $(s)$. Distillation under reduced pressure

State whether the following statements regarding fractional distillation are True or False:
$(i)$ The freezing of vapour of a liquid with a high boiling point takes place first.
$(ii)$ In the column,the more volatile liquid is present in a higher concentration in the vapour phase at higher levels.
$(iii)$ The condensed liquid flows down and provides heat to the vaporizing liquid.
$(iv)$ The liquid with the highest boiling point reaches the top of the column.

The species that exhibits the highest $R_f$ value in a thin layer chromatogram using a non-polar solvent on a silica gel plate is

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