$A$ reaction has an activation energy of $209 \, kJ \, mol^{-1}$. The rate increases $10$-fold when the temperature is increased from $27^{\circ} C$ to $X^{\circ} C$. The temperature $X$ is closest to
[Gas constant,$R = 8.314 \, J \, mol^{-1} \, K^{-1}$ ]

  • A
    $35$
  • B
    $40$
  • C
    $30$
  • D
    $45$

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For a particular reaction,the rate constant becomes double on increasing temperature from $27^{\circ} C$ to $37^{\circ} C$. Calculate the approximate activation energy (in $kcal \ mol^{-1}$,$R=2 \ cal \ mol^{-1} \ K^{-1}$).

For reaction $A \to B$,rate constant $K_1 = A_1 e^{-E_{a_1}/RT}$ and for the reaction $X \to Y$,rate constant $K_2 = A_2 e^{-E_{a_2}/RT}$. If $A_1 = 10^8, A_2 = 10^{10}$ and $E_{a_1} = 600 \ cal \ mol^{-1}$,$E_{a_2} = 1800 \ cal \ mol^{-1}$,then the temperature at which $K_1 = K_2$ is (given: $R = 2 \ cal \ K^{-1} \ mol^{-1}$):

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