$A$ solution of $KMnO_4$ on reduction yields either a colourless solution,a brown precipitate,or a green solution depending on the $pH$ of the solution. What different stages of the reduction do these represent and how are they carried out?

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The reduction of $KMnO_4$ depends on the $pH$ of the medium:
$1$. In acidic medium $(pH < 7)$: $MnO_4^-$ is reduced to $Mn^{2+}$ (colourless solution). The reaction is: $MnO_4^- + 8H^+ + 5e^- \rightarrow Mn^{2+} + 4H_2O$.
$2$. In neutral or faintly alkaline medium $(pH \approx 7)$: $MnO_4^-$ is reduced to $MnO_2$ (brown precipitate). The reaction is: $MnO_4^- + 2H_2O + 3e^- \rightarrow MnO_2 + 4OH^-$.
$3$. In strongly alkaline medium $(pH > 7)$: $MnO_4^-$ is reduced to $MnO_4^{2-}$ (green solution). The reaction is: $MnO_4^- + e^- \rightarrow MnO_4^{2-}$.

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$x, y$ and $z$ are respectively:
$MnO_4^- + x e^- \xrightarrow{\text{Alkaline medium}} MnO_4^{2-}$
$MnO_4^- + y e^- \xrightarrow{\text{Acidic medium}} Mn^{2+}$
$MnO_4^- + z e^- \xrightarrow{\text{Neutral medium}} MnO_2$

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Which of the following processes does not involve oxidation of iron?

Given below are two statements:
Statement-$I$ : Heating $NaCl$ with concentrated $H_2SO_4$ and $MnO_2$ results in oxidation of $Mn$.
Statement-$II$ : Heating $NaI$ with concentrated $H_2SO_4$ and $MnO_2$ results in reduction of $Mn$.
In light of the above statements, choose the most appropriate answer from the options given below:

$100 \ mL$ of $0.1 \ M$ $Fe^{2+}$ solution was titrated with $\frac{1}{60} \ M$ $Cr_2O_7^{2-}$ solution in acid medium. What is the volume (in $L$) of $Cr_2O_7^{2-}$ solution consumed?

When an acidic solution of $K_2Cr_2O_7$ is added to $Na_2SO_3$,it turns green. Which of the following compounds is formed in this reaction?

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