$A$ solution of two miscible liquids showing negative deviation from Raoult's law will have :

  • A
    increased vapour pressure,increased boiling point
  • B
    increased vapour pressure,decreased boiling point
  • C
    decreased vapour pressure,decreased boiling point
  • D
    decreased vapour pressure,increased boiling point

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$A$ mixture of toluene and benzene forms a nearly ideal solution. Assume $p_{B}^{\circ}$ and $p_{T}^{\circ}$ to be the vapour pressures of pure benzene and toluene,respectively. The slope of the line obtained by plotting the total vapour pressure versus the mole fraction of benzene is $....$

Identify the false statement among the following.

Liquids $A$ and $B$ form an ideal solution over the entire range of composition. At temperature $T$,an equimolar binary solution of liquids $A$ and $B$ has a vapour pressure of $45 \ Torr$. At the same temperature,a new solution of $A$ and $B$ having mole fractions $x_A$ and $x_B$,respectively,has a vapour pressure of $22.5 \ Torr$. The value of $x_A / x_B$ in the new solution is . . . . . (Given that the vapour pressure of pure liquid $A$ is $20 \ Torr$ at temperature $T$)

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