Addition of HCl does not obey Anti-Markovniko | vedclass

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(C) Anti-Markovnikov's addition (peroxide effect) involves the formation of free radicals. For the reaction to proceed via a free radical mechanism,th

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Its bond energy is high

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(C) Anti-Markovnikov's addition (peroxide effect) involves the formation of free radicals. For the reaction to proceed via a free radical mechanism,the $H-Cl$ bond must undergo homolytic cleavage. However,the $H-Cl$ bond has a very high bond dissociation energy. Therefore,the energy required to form $H^{\bullet}$ and $Cl^{\bullet}$ free radicals is not available,making the initiation step endothermic and unfavorable. Consequently,$HCl$ does not show the peroxide effect.

Addition of $HCl$ does not obey Anti-Markovnikov's rule because

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