Among the second period elements,the actual ionization enthalpies are in the order $Li < B < Be < C < O < N < F < Ne$. Explain why:
$(i)$ $Be$ has higher $\Delta_{i}H$ than $B$.
$(ii)$ $O$ has lower $\Delta_{i}H$ than $N$ and $F$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) $(i)$ During the process of ionization,the electron to be removed from a beryllium atom is a $2s$-electron,whereas the electron to be removed from a boron atom is a $2p$-electron.
$2s$-electrons are more strongly attracted to the nucleus than $2p$-electrons. Therefore,more energy is required to remove a $2s$-electron of beryllium than that required to remove a $2p$-electron of boron. Hence,beryllium has a higher $\Delta_{i}H$ than boron.
$(ii)$ In nitrogen $(1s^2 2s^2 2p^3)$,the three $2p$-electrons occupy three different atomic orbitals,representing a stable half-filled configuration. In oxygen $(1s^2 2s^2 2p^4)$,two of the four $2p$-electrons occupy the same $2p$-orbital,resulting in increased electron-electron repulsion. Consequently,the energy required to remove an electron from oxygen is less than that required for nitrogen.
Fluorine has a higher effective nuclear charge than oxygen due to an additional proton in the same shell. This results in a stronger attraction for valence electrons,making it harder to remove an electron from fluorine compared to oxygen. Thus,oxygen has a lower $\Delta_{i}H$ than both nitrogen and fluorine.

Explore More

Similar Questions

The angle between the lines represented by $y^2 \sin^2 \theta - xy \sin^2 \theta + x^2(\cos^2 \theta - 1) = 0$ is

Which reagent is commonly used in titration to determine the hardness of water?

Which one of the following gives a sooty flame on combustion?

Let $f(x)$ be defined for all $x > 0$ and be continuous. Let $f(x)$ satisfy $f(\frac{x}{y}) = f(x) - f(y)$ for all $x, y > 0$ and $f(e) = 1$. Then:

Two infinite length wires carry currents $8A$ and $6A$ respectively and are placed along the $X$ and $Y$-axes. The magnetic field at a point $P(0, 0, d) \ m$ will be:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo