An aromatic amine $(A)$ was treated with alcoholic potash and another compound $(Y)$ to form a foul-smelling gas with the formula $C_6H_5NC$. Compound $(Y)$ was formed by reacting a compound $(Z)$ with $Cl_2$ in the presence of slaked lime. The compound $(Z)$ is:

  • A
    $C_6H_5NH_2$
  • B
    $C_2H_5OH$
  • C
    $CH_3OCH_3$
  • D
    $CHCl_3$

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Compound $D$ is

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The product $(A)$ of the reaction is:

$(i)$ Write structures of different isomeric amines corresponding to the molecular formula,$C_{4}H_{11}N$. $(ii)$ Write $IUPAC$ names of all the isomers. $(iii)$ What type of isomerism is exhibited by different pairs of amines?

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Give a plausible explanation for each of the following:
$(i)$ Why are amines less acidic than alcohols of comparable molecular masses?
$(ii)$ Why do primary amines have higher boiling points than tertiary amines?
$(iii)$ Why are aliphatic amines stronger bases than aromatic amines?

In the hydrolysis of aniline,the reagent used is:

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