Arrange the following in order of $C-Br$ bond strength in a polar solvent. The structures are as follows:
$(I)$ $1$-methylcyclohexa-$2,4$-dienyl bromide
$(II)$ cyclohexa-$2,4$-dienyl bromide
$(III)$ $1$-methylcyclopenta-$2,4$-dienyl bromide
$(IV)$ cyclopenta-$2,4$-dienyl bromide

  • A
    $I < II < III < IV$
  • B
    $III < IV < I < II$
  • C
    $IV < III < II < I$
  • D
    $II < I < IV < III$

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An 'Assertion' $(A)$ and a 'Reason' $(R)$ are given below. Choose the correct answer from the following options.
Assertion $(A)$: Vinyl halides do not undergo nucleophilic substitution easily.
Reason $(R)$: Even though the intermediate carbocation is stabilized by loosely held $p-$ electrons,the cleavage is difficult because of strong bonding.

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$(1)$ The rate of reaction is independent of the concentration of the nucleophile.
$(2)$ The nucleophile attacks the $C$ atom on the side of the molecule opposite to the group being displaced.
$(3)$ The reaction proceeds with simultaneous bond formation and bond rupture/cleavage.
Amongst the following,which of the above are true?

In the following pairs of halogen compounds,which compound undergoes faster $S_N1$ reaction?
$(i)$ $2$-chloro-$2$-methylpropane and $3$-chloropentane
(ii) $2$-chloroheptane and $1$-chlorohexane

For a given alkyl group,the densities of the halides follow the order:

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