Assertion: Acetoacetic ester,CH_3COCH_2COOC_2 | vedclass

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Question

(D) Both Assertion and Reason are incorrect. Acetoacetic ester $(CH_3COCH_2COOC_2H_5)$ does not give a positive iodoform test under standard condition

Vedclass · Accepted Answer

If both the Assertion and Reason are incorrect.

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(D) Both Assertion and Reason are incorrect. Acetoacetic ester $(CH_3COCH_2COOC_2H_5)$ does not give a positive iodoform test under standard conditions because the active methylene group $(CH_2)$ between the two carbonyl groups is highly acidic and reactive,leading to cleavage rather than the formation of iodoform. The Reason is also incorrect because the structure of acetoacetic ester clearly contains the $CH_3CO-$ (acetyl) group.

Assertion: Acetoacetic ester,$CH_3COCH_2COOC_2H_5$,will give iodoform test.
Reason: It does not contain $CH_3CO-$ group.

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Assertion: Acetoacetic ester,$CH_3COCH_2COOC_2H_5$,will give iodoform test. Reason: It does not contain $CH_3CO-$ group.