Assuming complete ionisation,arrange the following solutions in order of increasing osmotic pressure.
$(a)$ $0.5 \ m \ Li_2SO_4$
$(b)$ $0.5 \ m \ KCl$
$(c)$ $0.5 \ m \ Al_2(SO_4)_3$
$(d)$ $0.1 \ m \ BaCl_2$

The size of a raw mango shrinks to a much smaller size when kept in a concentrated salt solution. Which one of the following processes can explain this?

$A$ solution of a nonvolatile solute is obtained by dissolving $0.8 \ g$ in $0.3 \ dm^3$ of water. The solution has an osmotic pressure of $0.2 \ atm$ at $300 \ K$. Calculate the molar mass of the solute. $[R = 0.082 \ atm \ dm^3 \ K^{-1} \ mol^{-1}]$

$A$ $40 \text{ g}$ non-electrolyte solute having a molar mass of $180 \text{ g mol}^{-1}$ is dissolved in water to form a solution. If the osmotic pressure of the solution is $2 \text{ atm}$ at $300 \text{ K}$, calculate the volume of the solution in $\text{dm}^3$. $(R = 0.0821 \text{ L atm K}^{-1} \text{mol}^{-1})$ (in $\text{ dm}^3$)

The osmotic pressure of $2.22\ \%\ (w/v)$ $CaCl_2$ solution at $27\ ^oC$ is $(R = 0.08\ L\ atm\ K^{-1}\ mol^{-1})$

Which solution is isotonic with $6 \% \ w/v$ aqueous solution of urea (in $M \ NaCl$)? [Molar mass of Urea $= 60 \ g \ mol^{-1}$]