Calculate $\Delta H$ when $2 \ moles$ of solid benzoic acid undergo complete combustion at $300 \ K$ if $C_6H_5COOH_{(s)} + \frac{15}{2} O_{2(g)} \rightarrow 7CO_{2(g)} + 3H_2O_{(l)}$,$\Delta U_{reaction} = -750 \ kJ/mole$ [$R = 8 \ J/mole \cdot K$].

  • A
    $-751.2$
  • B
    $-752.4$
  • C
    $-1501.2$
  • D
    $-1502.4$

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One mole of $CH_3OH$ is vaporized at $338 \ K$ and $1.5 \ atm$ pressure. If the enthalpy of vaporization of $CH_3OH$ is $35.57 \ kJ/mol$,calculate the value of $\Delta U$ for the process in $kJ$. (in $.76$)

For the reaction:
$CH_{4(g)} + 2O_{2(g)} \to CO_{2(g)} + 2H_2O_{(l)}$;
$\Delta_r H_{300} = -212.7 \ Kcal/mol$.
The absolute value of $\Delta_r U_{300}^o$ for this reaction is ....... $Kcal/mol$ $(R = 2 \ cal/mol-K)$.

For a spontaneous process, the correct statement$(s)$ is (are):

The enthalpy of neutralisation of $KOH$ by a weak acid $(HA)$ is $-12.2 \ kcal \ mol^{-1}$. If the weak acid is $10 \%$ ionised,then the enthalpy of dissociation of $1 \ mole$ of $HA$ is. Given that the enthalpy of neutralisation of $KOH$ by $HCl$ is $-13.7 \ kcal \ mol^{-1}$.

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Calculate $\Delta H^{\circ}$ for the reaction, $Na_2O_{(s)} + SO_{3(g)} \longrightarrow Na_2SO_{4(s)}$, given the following reactions:
$(A) \ Na_{(s)} + H_2O_{(l)} \longrightarrow NaOH_{(s)} + \frac{1}{2}H_{2(g)} \quad \Delta H^{\circ} = -146 \ kJ$
$(B) \ Na_2SO_{4(s)} + H_2O_{(l)} \longrightarrow 2NaOH_{(s)} + SO_{3(g)} \quad \Delta H^{\circ} = +418 \ kJ$
$(C) \ 2Na_2O_{(s)} + 2H_{2(g)} \longrightarrow 4Na_{(s)} + 2H_2O_{(l)} \quad \Delta H^{\circ} = +259 \ kJ$

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