Calculate the enthalpy of formation of carbon monoxide $(CO).$ Given: $C_{(s)} + O_{2(g)} \rightarrow CO_{2(g)}, \Delta H = -393.3 \ kJ \ mol^{-1}$ and $CO_{(g)} + \frac{1}{2} O_{2(g)} \rightarrow CO_{2(g)}, \Delta H = -282.2 \ kJ \ mol^{-1}.$
- A$-111.1 \ kJ \ mol^{-1}$
- B$676.1 \ kJ \ mol^{-1}$
- C$-282.8 \ kJ \ mol^{-1}$
- D$300.0 \ kJ \ mol^{-1}$
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From the following bond energies:
$H-H$ bond energy $431.37 \text{ kJ mol}^{-1}$ $C=C$ bond energy $606.10 \text{ kJ mol}^{-1}$ $C-C$ bond energy $336.49 \text{ kJ mol}^{-1}$ $C-H$ bond energy $410.50 \text{ kJ mol}^{-1}$
Enthalpy for the reaction $CH_2=CH_2 + H-H \to CH_3-CH_3$ will be .............. $\text{kJ mol}^{-1}$
| $H-H$ bond energy | $431.37 \text{ kJ mol}^{-1}$ |
| $C=C$ bond energy | $606.10 \text{ kJ mol}^{-1}$ |
| $C-C$ bond energy | $336.49 \text{ kJ mol}^{-1}$ |
| $C-H$ bond energy | $410.50 \text{ kJ mol}^{-1}$ |
Enthalpy for the reaction $CH_2=CH_2 + H-H \to CH_3-CH_3$ will be .............. $\text{kJ mol}^{-1}$
MediumAIPMT 2009
View SolutionThe enthalpy of combustion of benzene from the following data will be
$(i) \ 6C_{(s)} + 3H_{2(g)} \to C_6H_{6(l)} ; \Delta H = +45.9 \ kJ$
$(ii) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)} ; \Delta H = -285.9 \ kJ$
$(iii) \ C_{(s)} + O_{2(g)} \to CO_{2(g)} ; \Delta H = -393.5 \ kJ$
.....$kJ$
$(i) \ 6C_{(s)} + 3H_{2(g)} \to C_6H_{6(l)} ; \Delta H = +45.9 \ kJ$
$(ii) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)} ; \Delta H = -285.9 \ kJ$
$(iii) \ C_{(s)} + O_{2(g)} \to CO_{2(g)} ; \Delta H = -393.5 \ kJ$
.....$kJ$
Medium
View SolutionThe bond dissociation energies of $X_2$,$Y_2$ and $XY$ are in the ratio of $1 : 0.5 : 1$. $\Delta H$ for the formation of $XY$ is $-200 \ kJ \ mol^{-1}$. The bond dissociation energy of $X_2$ will be $...... \ kJ \ mol^{-1}$.
From the given data at $298 \, K$:
$\Delta H_f^o [CO_2, g] = -394 \, kJ/mol$
$\Delta H_f^o [H_2O, l] = -286 \, kJ/mol$
$\Delta H_f^o [propene, g] = 20 \, kJ/mol$
$cyclopropane (g) \to propene (g)$; $\Delta H^o_{isomerisation} = -33 \, kJ/mol$.
Calculate $\Delta H^o_{combustion} [cyclopropane, g]$.
$...... \, kJ/mol$
$\Delta H_f^o [CO_2, g] = -394 \, kJ/mol$
$\Delta H_f^o [H_2O, l] = -286 \, kJ/mol$
$\Delta H_f^o [propene, g] = 20 \, kJ/mol$
$cyclopropane (g) \to propene (g)$; $\Delta H^o_{isomerisation} = -33 \, kJ/mol$.
Calculate $\Delta H^o_{combustion} [cyclopropane, g]$.
$...... \, kJ/mol$
Difficult
View SolutionThe heats of combustion of rhombic and monoclinic sulphur are respectively $70960 \ cal$ and $71030 \ cal$. What will be the heat of conversion of rhombic sulphur to monoclinic? $(cal)$
Medium
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