Calculate the molality of the solution of a nonvolatile solute if it freezes at $-0.36 \ ^{\circ}C$. [Given: $K_{f}$ for solvent $= 1.86 \ K \ kg \ mol^{-1}$]

$83 \ g$ of ethylene glycol is dissolved in $625 \ g$ of water. The freezing point of the solution is $...... \ K$. (Nearest integer) [Use: Molal freezing point depression constant of water $= 1.86 \ K \ kg \ mol^{-1}$,Freezing point of water $= 273 \ K$,Atomic masses: $C = 12.0 \ u, O = 16.0 \ u, H = 1.0 \ u$]

$A$ $5\%$ solution (by mass) of cane sugar in water has a freezing point of $271 \ K$ and the freezing point of pure water is $273.15 \ K$. The freezing point of a $5\%$ solution (by mass) of glucose in water is ............. $K$.

Ethylene glycol is used as an antifreeze in cold climates. The mass of ethylene glycol $(C_2H_6O_2)$ that should be added to $4 \ kg$ of water to prevent it from freezing at $-6 \ ^oC$ is ......... $g$.
($K_f$ for water $= 1.86 \ K \ kg \ mol^{-1}$,and molar mass of ethylene glycol $= 62 \ g \ mol^{-1}$)

Identify $(i)$,$(ii)$ and $(iii)$ in the following diagram representing the depression in freezing point:

Calculate the molal depression constant of a solvent, which freezes at $15^{\circ}C$. The latent heat of fusion is $180.7 \ Jg^{-1}$.