Carbon and silicon both belong to group $14$, but despite the stoichiometric similarity, their dioxides (i.e., carbon dioxide and silicon dioxide) differ in their structures. Comment.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) In $CO_{2}$, the carbon atom undergoes $sp$ hybridization. Two $sp$ hybridized orbitals of the carbon atom overlap with two $p$ orbitals of oxygen atoms to form two sigma bonds, while the other two electrons of the carbon atom are involved in $p\pi-p\pi$ bonding with oxygen atoms.
This results in a linear shape [with both $C-O$ bonds of equal length $(115 \ pm)$] with no dipole moment. Carbon can form a double bond with oxygen due to its small size.
Silicon dioxide is a covalent, three-dimensional network solid in which each silicon atom is covalently bonded in a tetrahedral manner to four oxygen atoms. Each oxygen atom is, in turn, covalently bonded to another silicon atom.
Each corner is shared with another tetrahedron. The entire crystal may be considered a giant molecule in which eight-membered rings are formed with alternate silicon and oxygen atoms. Silicon cannot form a stable $p\pi-p\pi$ double bond with oxygen due to its large size and lower electronegativity compared to carbon.

Explore More

Similar Questions

Which of the following is the pyrosilicate ion?

Carborundum is obtained when silica is heated at high temperature with

Monosilane,on coming in contact with air,burns with a luminous flame producing vortex rings. These rings are of:

Assertion $(A)$: The maximum covalency of $Si$ and $Ge$ is $6$ but that of carbon is $4$.
Reason $(R)$: Due to the presence of $d$-orbitals in $Si$ and $Ge$,both these elements can undergo $sp^3d^2$ hybridisation and covalency of $6$ is possible. Carbon has no $d$-orbitals in it and hence its covalency is $4$.
The correct answer is:

What is the formula of the product formed when $F^{-}$ reacts with enamel on teeth?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo