Certain bimolecular reactions which follow the first order kinetics are called

  • A
    First order reactions
  • B
    Unimolecular reactions
  • C
    Bimolecular reactions
  • D
    Pseudounimolecular reactions

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Assertion : The kinetics of the reaction $mA + nB + pC \to m'X + n'Y + p'Z$ obey the rate expression as $\frac{dX}{dt} = k[A]^m[B]^n$.
Reason : The rate of the reaction does not depend upon the concentration of $C$.

The following data are obtained for a reaction,$X + Y \rightarrow$ Products.
$Expt.$ $[X]_0 / mol \ L^{-1}$ $[Y]_0 / mol \ L^{-1}$ $Rate / mol \ L^{-1} s^{-1}$
$1$ $0.25$ $0.25$ $1.0 \times 10^{-6}$
$2$ $0.50$ $0.25$ $4.0 \times 10^{-6}$
$3$ $0.25$ $0.50$ $8.0 \times 10^{-6}$

The overall order of the reaction is:

The value of $\frac{t_{0.875}}{t_{0.50}}$ for $n^{th}$ order reaction is

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What is the order of the following reaction: $2H_2O_2(l) \rightarrow 2H_2O(l) + O_2(g)$, given that the rate law is $\text{rate} = k[H_2O_2]^1$?

The rate for the reaction $A + B \rightarrow \text{product}$ is $1.8 \times 10^{-2} \ mol \ dm^{-3} \ s^{-1}$. Calculate the rate constant if the reaction is second order in $A$ and first order in $B$,given $[A] = 0.2 \ M$ and $[B] = 0.1 \ M$.

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